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CasNo: 57103-01-2
MF: C14H13NO2
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methanol
3,6-dibromo-9H-carbazole
3,6-di-methoxy-9H-carbazole
Conditions | Yield |
---|---|
methanol;
With
sodium;
at 0 - 20 ℃;
for 2h;
Inert atmosphere;
Schlenk technique;
3,6-dibromo-9H-carbazole;
With
copper(l) iodide;
In
N,N-dimethyl-formamide;
at 80 ℃;
for 24h;
Inert atmosphere;
Schlenk technique;
|
85% |
With
copper(l) iodide; sodium;
In
N,N-dimethyl-formamide;
at 120 ℃;
for 3h;
Inert atmosphere;
|
62% |
With
copper(l) iodide; sodium methylate;
In
N,N-dimethyl-formamide;
Inert atmosphere;
Schlenk technique;
|
62% |
With
sodium methylate; copper(I) bromide;
Reflux;
|
|
With
copper(l) iodide; sodium methylate;
In
N,N-dimethyl-formamide;
|
methanol
3,6-dibromo-9H-carbazole
sodium methylate
3,6-di-methoxy-9H-carbazole
Conditions | Yield |
---|---|
With
copper(l) iodide;
In
methanol; N,N-dimethyl-formamide;
at 120 ℃;
for 12h;
Inert atmosphere;
|
78% |
With
copper(l) iodide;
In
N,N-dimethyl-formamide;
at 120 ℃;
for 20h;
Inert atmosphere;
Sealed tube;
|
61.5% |
With
copper(l) iodide;
In
N,N-dimethyl-formamide;
at 120 ℃;
for 20h;
Inert atmosphere;
Schlenk technique;
Sealed tube;
|
52% |
3,6-dibromo-9H-carbazole
sodium methylate
9H-carbazole
methanol